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Thulium 170

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Thulium-170: A Deep Dive into the Rare Earth Isotope with Powerful Applications



The world of rare earth elements often remains shrouded in mystery, despite their critical role in modern technologies. One such element, thulium, specifically its isotope Thulium-170 (¹⁷⁰Tm), is quietly revolutionizing various fields, yet its potential remains largely untapped. While not as widely known as other rare earths like neodymium or cerium, ¹⁷⁰Tm possesses unique properties that make it a powerful tool with applications ranging from portable X-ray sources to cancer therapy. This article aims to demystify ¹⁷⁰Tm, exploring its properties, applications, and future prospects.


Understanding Thulium-170: Properties and Production



Thulium is a naturally occurring rare earth element, but ¹⁷⁰Tm isn't found in abundance in nature. It's a radioactive isotope, meaning it decays over time, emitting radiation. This decay process is what makes it so valuable in various applications. Specifically, ¹⁷⁰Tm is a beta emitter, releasing high-energy beta particles (electrons) and gamma rays. The energy of these emissions is crucial for its usefulness. The half-life of ¹⁷⁰Tm is approximately 128.6 days, a relatively short duration compared to other radioactive isotopes, requiring regular replenishment for continuous operation in devices.

Production of ¹⁷⁰Tm involves irradiating the more abundant stable isotope ¹⁶⁹Tm with neutrons in a nuclear reactor. This process, known as neutron activation, converts ¹⁶⁹Tm into ¹⁷⁰Tm. The purity of the resulting ¹⁷⁰Tm is crucial for its applications, requiring advanced separation and purification techniques. The process is energy-intensive and contributes to the high cost of ¹⁷⁰Tm-based products. Furthermore, the supply chain is heavily reliant on a limited number of nuclear reactors capable of performing this neutron activation.


Applications of Thulium-170: From Medicine to Industry



The unique properties of ¹⁷⁰Tm's radiation make it particularly suitable for several applications:

1. Portable X-ray Sources: The high-energy beta particles emitted by ¹⁷⁰Tm can be converted into X-rays using a process called Bremsstrahlung radiation. This allows for the development of compact and portable X-ray devices, ideal for applications in remote areas, security checkpoints, and non-destructive testing (NDT). These portable X-ray machines are significantly smaller and lighter than traditional X-ray systems relying on larger and more complex X-ray tubes. This portability is critical for field applications, such as geological surveys or pipeline inspections.

2. Radioisotope Thermoelectric Generators (RTGs): While primarily known for using isotopes like plutonium, RTGs can also utilize ¹⁷⁰Tm's decay heat to generate electricity. Though the power output is relatively lower compared to plutonium-based RTGs, the shorter half-life and reduced radioactivity levels of ¹⁷⁰Tm offer advantages in specific applications where minimizing long-term radioactive waste is paramount. This makes it a potential candidate for specialized remote sensing devices or low-power space missions.

3. Cancer Therapy (Brachytherapy): ¹⁷⁰Tm's beta radiation, with its relatively short range, makes it suitable for brachytherapy, a type of cancer treatment where radioactive sources are placed directly into or near the tumor. The short range minimizes damage to surrounding healthy tissues, making it a promising option for various cancers. Ongoing research explores its effectiveness and potential advantages over other brachytherapy isotopes.

4. Industrial Gauging: The ability of ¹⁷⁰Tm to emit both beta and gamma radiation is utilized in industrial gauging applications. For example, it can be used in measuring the thickness of materials in real-time, crucial in manufacturing processes requiring precise control of material properties.


Challenges and Future Prospects



Despite its promising applications, ¹⁷⁰Tm faces several challenges:

High Cost: The specialized production process and limited availability contribute to the high cost of ¹⁷⁰Tm, hindering its widespread adoption.
Short Half-Life: The 128.6-day half-life requires frequent replacement of ¹⁷⁰Tm sources, increasing operational costs and logistical complexities.
Radiation Safety: Handling radioactive materials requires stringent safety protocols and specialized training to prevent exposure to harmful radiation.


Future research focuses on optimizing the production process to reduce costs and improving the design of ¹⁷⁰Tm-based devices to enhance efficiency and minimize waste. The exploration of new applications, particularly in the field of medicine, continues to drive interest in this fascinating isotope. Advanced material science and improved radiation shielding technologies could help to overcome some of the current limitations.


Conclusion



Thulium-170, despite its relative obscurity, represents a valuable tool with significant potential across diverse fields. Its unique radiation properties offer advantages in portable X-ray sources, radioisotope thermoelectric generators, cancer therapy, and industrial gauging. While challenges related to cost, half-life, and radiation safety remain, ongoing research and development are paving the way for wider adoption and unlocking the full potential of this remarkable rare earth isotope.


FAQs



1. Is Thulium-170 dangerous? Yes, ¹⁷⁰Tm is radioactive and emits ionizing radiation. Proper handling and shielding are essential to prevent exposure and minimize health risks. Exposure limits are strictly regulated to ensure safety.

2. What is the difference between Thulium-170 and other radioactive isotopes used in similar applications? ¹⁷⁰Tm's relatively short half-life and the specific energy of its beta and gamma emissions differentiate it from other isotopes. This makes it particularly suitable for certain applications where portability, reduced long-term waste, or a specific radiation profile are required.

3. How is Thulium-170 disposed of? Disposal of ¹⁷⁰Tm requires adherence to strict regulations and procedures. Specialized facilities are responsible for the safe and secure disposal of radioactive waste, ensuring minimal environmental impact.

4. What are the future research directions for Thulium-170? Future research focuses on developing more efficient and cost-effective production methods, improving the design of ¹⁷⁰Tm-based devices, exploring new applications in medicine and other fields, and enhancing radiation shielding technologies.

5. Where can I find Thulium-170 sources? ¹⁷⁰Tm is not readily available to the general public. Its acquisition is tightly regulated and requires special permits and licenses due to its radioactive nature. Only authorized organizations and institutions with appropriate safety protocols can procure and utilize it.

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Thulium-170 heat source (Technical Report) - OSTI.GOV 6 Sep 1990 · An isotopic heat source is formed using stacks of thin individual layers of a refractory isotopic fuel, preferably thulium oxide, alternating with layers of a low atomic weight diluent, preferably graphite.

Thulium-170 | chemical isotope | Britannica - Encyclopedia Britannica …neutrons, natural thulium becomes radioactive thulium-170 (128.6-day half-life), which ejects soft gamma radiation with wavelength commensurate with laboratory hard X-ray sources. Only one allotropic (structural) form is known for thulium.

Thulium-170 - isotopic data and properties - chemlin.org Properties and data of the isotope 170 Tm. Thulium isotopes. ½ 128.6 (3) d 1.1111040 × 107 seconds s. The following table shows the atomic nuclei that are isotonic (same neutron number N = 101) and isobaric (same nucleon number A = 170) with Thulium-170.

Thulium-170 - Wikipedia Thulium-170 (170Tm or Tm-170) is a radioactive isotope of thulium proposed for use in radiotherapy and in radioisotope thermoelectric generators. Thulium-170 has a binding energy of 8 105.5144 (43) keV per nucleon and a half-life of 128.6 ± 0.3 d.

Thulium-170 | Tm | CID 161009 - PubChem 14 Oct 2021 · Thulium-170 | Tm | CID 161009 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more.

Calorimetrically measured half-life of thulium-170 - ScienceDirect A half-life of 128 ± 1 days for thulium-170 was determined calorimetrically. Two 170 Tm sources of about 1 W each were measured for 140 days. The sources were produced by neutron irradiation of 169 Tm 2 O 3 wafers, to a specific power of ∼ 2 W/g.

Isotopes of thulium - Wikipedia Thulium-170 has a half-life of 128.6 days, decaying by β − decay about 99.87% of the time and electron capture the remaining 0.13% of the time. [1] Due to its low-energy X-ray emissions, it has been proposed for radiotherapy [6] and as a source in a radiothermal generator. [7]

Production, quality control and biodistribution studies of thulium-170 ... In this study 170 Tm was produced using Tm (NO 3) 3, prepared by neutron activation (3–4E13) of a natural sample. Ethylenediamine (tetramethylene phosphonic acid) (EDTMP) was synthesized and radiolabeled with 170 Tm. Complexation parameters …

Transmission electron microscope image of the 170 Abstract The present article describes the preparation, characterization, and biological evaluation of Thulium-170 ((170)Tm) [T1/2=128.4 days; Eβ(max)=968 keV; Eγ=84 keV (3.26%)] labeled...

IYPT 2019 Elements 069: Thulium: Portable X-rays and banknotes 17 Sep 2019 · One of thulium’s isotopes, thulium-170, can be used as a radioactive source in portable X-ray machines. These machines have a useful life of around a year. Thulium-170 has also been investigated as a potential treatment for some types of cancer.

Thulium-170-labeled microparticles for local radiotherapy The present article describes the preparation, characterization, and biological evaluation of Thulium-170 ((170)Tm) [T1/2 = 128.4 days; Eβmax = 968 keV; Eγ = 84 keV (3.26%)] labeled tin oxide microparticles for its possible use in radiation synovectomy (RSV) of medium-sized joints.

Infrastructure for thulium-170 isotope power systems for … 1 Jul 1991 · The radioisotope thulium-170 is a safe and environmentally benign heat source for providing the high endurance and energy densities needed by advanced power systems for autonomous underwater vehicles (AUV).

Thulium - Wikipedia Despite its high cost, portable X-ray devices use thulium that has been bombarded with neutrons in a nuclear reactor to produce the isotope Thulium-170, having a half-life of 128.6 days and five major emission lines of comparable intensity (at 7.4, 51.354, 52.389, 59.4 and 84.253 keV).

(PDF) Thulium-170-Labeled Microparticles for Local Radiotherapy ... 3 Oct 2014 · These preliminary studies showed that (170)Tm-labeled microparticles could be a promising nontoxic and effective radiopharmaceutical for RSV applications or later local antitumor therapy.

Atomic Beam Study of the Hyperfine Structure of Thulium-170 The atomic-beam magnetic-resonance technique has been used to measure atomic and nuclear quantities of the 129-day isotope Tm 170 as follows: J = 7 2, g J = 1.14122 ± 0.00015, I = 1, | A | = 200 ± 3 Mc/sec, and | B | = 1010 ± 15 Mc/sec. The values of J and g J are consistent with the ground-state assignment F 7 2 2.

Chapter 10 Thulium-170 radiopharmaceuticals for bone pain … Thulium-170 is presented as a promising radiopharmaceutical for palliation of bone pain due to metastatic cancers. Its physical and chemical properties are analyzed, highlighting advantages over other radionuclides like Strontium-89, particularly in terms of lower beta energy and suitable gamma emissions for imaging.

Thulium Facts, Symbol, Discovery, Properties, Uses - Chemistry … Thulium-170 (170 Tm), a radioactive isotope formed by bombarding thulium in a nuclear reactor, can be used as a portable source of radiation in medical x-ray machines [1, 7]. The element 69 is used as a dopant in fiber lasers for surgical applications [1, 3].

Thulium-170 | 13981-30-1 - ChemicalBook Thulium-170 | 13981-30-1 - chemical and physical properties, structure, melting point, boiling point, density, molecular formula, molecular weight, uses, prices, suppliers, and toxicity/safety/hazards/SDS information.

Feasibility of Thulium‐170, Produced on Site, for Radioisotope … 1 Jul 1994 · Thulium‐170 has been suggested as a replacement for 238 Pu jn some radioisotope power generation applications. The proposed approach is to activate 169 Tm within the core or reflector of a stationary site power nuclear reactor at a Lunar or Mars outpost.