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1 4 Dimethylbenzene Common Name

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1,4-Dimethylbenzene: Unpacking the Common Name and Beyond



1,4-Dimethylbenzene, a simple yet significant aromatic hydrocarbon, finds application in various industries. Understanding its common name, properties, and uses is crucial for anyone involved in chemistry, chemical engineering, or related fields. This article delves into the world of 1,4-dimethylbenzene, answering key questions regarding its identity, properties, and applications.

I. What is the Common Name of 1,4-Dimethylbenzene?

The systematic IUPAC name, 1,4-dimethylbenzene, accurately describes its structure: a benzene ring (a six-carbon aromatic ring) with two methyl groups (-CH3) attached at positions 1 and 4, opposite each other. However, this isn't the name most commonly used in everyday conversation or industrial settings. The common name for 1,4-dimethylbenzene is para-xylene (or simply p-xylene). The "para" prefix refers to the 1,4- (or para) positions of the substituents on the benzene ring. This naming convention applies to other disubstituted benzene derivatives as well (ortho- for 1,2- and meta- for 1,3-).

II. What are the Key Physical and Chemical Properties of Para-Xylene?

Para-xylene is a colorless, flammable liquid with a characteristic aromatic odor. Its key properties include:

Melting Point: Relatively low, around 13°C (55°F). This means it's a solid at room temperature only under certain conditions.
Boiling Point: 138°C (280°F). This determines how it behaves in distillation processes.
Solubility: Insoluble in water but soluble in many organic solvents like ether, ethanol, and benzene. This dictates its handling and separation techniques.
Reactivity: Para-xylene undergoes typical aromatic reactions like nitration, sulfonation, and Friedel-Crafts alkylation. These reactions are essential in its conversion to valuable products.
Density: Less dense than water, meaning it will float on water, a crucial safety consideration in spills.

III. How is Para-Xylene Produced and Purified?

Para-xylene is primarily obtained from petroleum refining. It's a component of the xylene isomers (ortho-, meta-, and para-xylene) found in petroleum fractions. The challenge lies in separating para-xylene from its isomers, as they have very similar boiling points. This separation is crucial because para-xylene is the most commercially valuable isomer.

Several methods are employed for purification, including:

Fractional Distillation: This is a basic technique but isn't sufficient for complete separation due to the isomers' similar boiling points.
Crystallisation: Exploiting the relatively high melting point of para-xylene, it can be separated by cooling and filtering the solid crystals.
Adsorptive separation: Using zeolites or other adsorbents that preferentially adsorb para-xylene, allowing for its separation.

These methods are often used in combination to achieve high purity para-xylene.

IV. What are the Main Applications of Para-Xylene?

Para-xylene is a cornerstone chemical used extensively in the production of several important materials:

Terephthalic acid (TPA): This is the most significant application. TPA is oxidized from para-xylene and is the primary building block for polyethylene terephthalate (PET), a ubiquitous plastic used in beverage bottles, clothing fibers (polyester), and food packaging.
Dimethyl terephthalate (DMT): Another important derivative used in the production of PET.
Other specialized chemicals: Para-xylene is also a precursor for various other chemicals used in the production of paints, solvents, and other specialized materials.

V. Environmental Considerations and Safety Precautions

Para-xylene, like other aromatic hydrocarbons, is a volatile organic compound (VOC). Its release into the atmosphere can contribute to air pollution and the formation of smog. Proper handling, storage, and industrial emissions control are vital to minimize environmental impact. Direct exposure can cause skin and eye irritation and, in high concentrations, respiratory problems. Appropriate safety measures, including personal protective equipment (PPE) and proper ventilation, must always be followed when handling para-xylene.


Conclusion:

1,4-Dimethylbenzene, commonly known as para-xylene, is a crucial chemical intermediate with widespread applications. Its unique properties, particularly its ability to be converted into terephthalic acid, make it an essential component in the production of various plastics and fibers used in countless everyday products. Understanding its chemical characteristics, production methods, and environmental impact is paramount for sustainable industrial practices and responsible chemical handling.


FAQs:

1. What is the difference between para-xylene, meta-xylene, and ortho-xylene? The difference lies in the position of the two methyl groups on the benzene ring: para-xylene has them opposite (1,4), meta-xylene has them at 1,3 positions, and ortho-xylene at 1,2 positions. This difference significantly impacts their reactivity and resulting products.

2. Can para-xylene be directly used in consumer products? No, para-xylene itself is rarely found in consumer products. It's primarily used as a raw material to produce other chemicals, such as TPA, which are then used in consumer goods.

3. What are the health risks associated with long-term exposure to para-xylene? Chronic exposure can potentially lead to liver and kidney damage, as well as neurological effects. The severity depends on concentration and duration of exposure.

4. How is the purity of para-xylene measured? Purity is typically assessed using techniques like gas chromatography (GC) and high-performance liquid chromatography (HPLC), which accurately determine the concentration of para-xylene relative to its isomers and other impurities.

5. What are the future prospects for para-xylene production and its applications? With the growing demand for PET plastics and polyester fibers, the demand for para-xylene is expected to continue rising. Research is ongoing to improve the efficiency and sustainability of its production and to explore new applications for this valuable chemical.

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p-Xylene - Wikipedia p-Xylene (para-xylene) is an aromatic hydrocarbon. It is one of the three isomers of dimethylbenzene known collectively as xylenes. The p- stands for para-, indicating that the two methyl groups in p -xylene occupy the diametrically opposite substituent positions 1 and 4.

Benzene Derivatives and Their Nomenclature in Organic Chemistry 1 Sep 2014 · Many simple monosubstituted derivatives of benzene have common names of long standing that have been retained in the IUPAC system. Dimethyl derivatives of benzene are called xylenes. There are three xylene isomers, the ortho (o)-, meta (m)-, and para ( p)- …

4.10: Benzene and its Derivatives - Chemistry LibreTexts 26 Jul 2022 · For this reason, the OMP system will yield common names that can be converted to systematic names by using the same method as above. For example, o-Xylene from the OMP system can be named 1,2-dimethylbenzene by using simple benzene naming (IUPAC standard).

P-Xylene | C6H4(CH3)2 | CID 7809 - PubChem Used as a chemical intermediate for the synthesis of 1,4-bis(chloromethyl)benzene; dimethyl terephthalate; poly-p-xylylene; terephthalic acid; 4-(tri-fluoromethyl)benzaldehyde; 4-(trifluoromethyl)benzyl alcohol; 2,5-xylidine.

XYLENE (ALL ISOMERS) - ACGIH Synonyms: 1,3-Dimethylbenzene; o-Dimethylbenzene, m-Methyl toluene; 1,3-Xylene; meta-Xylene; m-Xylol Structural formula: (National Center for Biotechnology Information (NCBI; US) 2005c)

IV.1.4. aromatic hydrocarbons (benzene derivatives) IV.1.4. aromatic hydrocarbons (benzene derivatives): Unlike aliphatic organics, nomenclature of benzene-derived compounds can be confusing because a single aromatic compound can have multiple possible names (such as common and systematic names) be associated with its structure. In these sections, we will analyze some of

p-Xylene | C8H10 - ChemSpider ChemSpider record containing structure, synonyms, properties, vendors and database links for p-Xylene, 106-42-3, URLKBWYHVLBVBO-UHFFFAOYSA-N

p-Xylene - NIST Chemistry WebBook Other names: Benzene, 1,4-dimethyl-; p-Dimethylbenzene; p-Xylol; 1,4-Dimethylbenzene; 1,4-Xylene; p-Methyltoluene; para-Xylene; Chromar; Scintillar; 4-Methyltoluene; NSC 72419; UN 1307; 1,4-dimethyl-benzene ( p-xylene) Permanent link for this species. Use this link for bookmarking this species for future reference.

Xylene - Uses, Formula, Structure, FAQs - Careers360 23 Jun 2022 · Xylene or dimethyl benzene is a highly flammable colorless liquid with a chemical formula (CH 3) 2 C 6 H 4. As the name dimethyl benzene suggested, it is a compound where the benzene ring has been substituted by 2 methyl groups.

1,4-dimethylbenzene - (Organic Chemistry) - Fiveable 1,4-dimethylbenzene, also known as p-xylene, is an aromatic hydrocarbon compound with two methyl groups attached to a benzene ring in the para position. It is an important industrial chemical and a precursor for various organic compounds.